MTA-BME Lendület Sustainable Polymers Research Group

Project summary

Closing the product life cycle loop through recycling and reuse is the key to transitioning to a circular economy. This project will address the challenges of establishing a circular economy for all types of polymers, from sourcing during production to monitoring and repair during use, to recycling and functional redesign at end-of-life. The main challenge in sustainable polymer design is to create inherently recyclable thermoset polymers and recyclable thermoplastic polymer systems for structural applications. The project aims to develop recyclable vitrimer systems and thermoset polymers from potentially renewable sources for high-performance composites and self-reinforced polymer composites from ε-caprolactam for potential replacement of short-fibre reinforced polyamide 6 composites. Extending lifespan can be a relevant strategy for structural polymer composites to minimise their environmental impact. The project aims to develop durable and damage-tolerant composite structures, improve non-destructive testing methods, integrate sensors for continuous monitoring, and include healing and repair capabilities. As the mechanical recycling of thermoplastics is a well-established technology, the focus of this research is to identify sustainable recycling methods for difficult-to-recycle polymer systems for which industrial-scale solutions have not yet been developed, including innovative polymer matrices, fibre reinforcement and polymer additives. The underutilization of sustainable strategies in product design leads to the downcycling of polymer waste. We will develop value-added safe-by-design recycled and recyclable polymers and composites by upcycling and methods for predicting and modelling their properties.

Project results

Project-related publications

1. 
   Nemes-Károly I., Szebényi G.: DEVELOPMENT OF SINTERED ALL-UHMWPE COMPOSITES FOR JOINT IMPLANT SOCKETS. in 'ECCM21 - 21st European Conference on Composite Materials Nantes, Franciaország. 2024.07.02-2024.07.05.,1119-1125 (2024)
2. 
   Kovács Zs., Toldy A.: Synergistic flame retardant coatings for carbon fibre-reinforced polyamide 6 composites based on expandable graphite, red phosphorus, and magnesium oxide. Polymer Degradation and Stability, 222, 110696/1-110696/ (2024) 10.1016/j.polymdegradstab.2024.110696 IF=6.3 D1
3. 
   Czél G.: Direct comparison of novel unidirectional sandwich coupon designs for accurate tensile failure strain determination of carbon fibre epoxy material. in 'ECCM21 – 21st European Conference on Composite Materials Nantes, Franciaország . 2024.07.02.-05.,Vol 4. 25-32 (2024)
4. 
   Marton G. Zs., Fendrik Á., Szebényi G.: Manufacturing of composites with designed failure. IOP Conference Series: Materials Science and Engineering, 1313, 012014/1-012014/9 (2024) 10.1088/1757-899X/1313/1/012014
5. 
   Dózsa G., Sántha P., Tamás-Bényei P.: Fehér töltőanyagot tartalmazó gumikeverékek fejlesztése. Polimerek, X. évf., 34-40 (2024)
6. 
   Kovács Zs., Toldy A.: Development of flame retardant coatings containing hexaphenoxycyclotriphosphazene and expandable graphite for carbon fibre-reinforced polyamide 6 composites. Polymer Degradation and Stability, 230, 111017 (2024) 10.1016/j.polymdegradstab.2024.111017 IF=6.3 D1
7. 
   Gere D., Pomázi F., Szöllősi A., Jahanpeyma P., Ermilov A. A., Baranya S., Toldy A.: Mikroműanyag szennyezés vizsgálata a Duna budapesti szakaszán. Polimerek, 2, 66-72 (2024)
8. 
   Szebényi G., Marton G. Zs., Romhány G.: Damage localization in designed failure composites. in 'ECCM21 – 21st European Conference on Composite Materials Nantes, Franciaország. 2024.07.02-2024.07.05.,156-160 (2024)
9. 
   Kovács Zs., Toldy A.: Flame retardant coatings for E-caprolactam-based self-reinforced polyamide 6 composites. in 'ECCM21 – 21st European Conference on Composite Materials Nantes, Franciaország. 2024.07.02.-05.,989-995 (2024)
10. 
    Toldy A., Poór D. I., Szolnoki B., Devecser B., Geier N., Pomázi Á.: Comparative study of flame retardancy in polyimine vitrimers and composites: Evaluating additive and reactive flame retardants acting via gas-, solid-, and combined-phase mechanisms. Journal of Materials Science & Technology, 196, 101-111 (2024) 10.1016/j.jmst.2024.01.047 IF=11.2 D1
11. 
    Budavári B., Karancsi Á., Pinke B. G., Pállinger É., Juriga-Tóth K., Király M., Szász Zs., Voszka I., Molnár K., Kőhidai L., Jedlovszky-Hajdú A., S Nagy K.: Long-term shelf-life liposomes for delivery of prednisolone and budesonide. Journal of Molecular Liquids , 394, 123756/1-123756/13 (2024) 10.1016/j.molliq.2023.123756 IF=5.3 Q1
12. 
    Marton G. Zs., Szebényi G.: The effect of pattern width on the properties and behavior of interfacially engineered composites with designed failure. in 'ECCM21 – 21st European Conference on Composite Materials Nantes, Franciaország. 2024.07.02-2024.07.05.,1438-1443 (2024)
13. 
    Poór Dániel István, Tobey Marina, Taynton Philip, Pomázi Ákos, Toldy Andrea, Geier Norbert: A comparative machinability analysis of polyimine vitrimer, epoxy and polycarbonate polymers through orthogonal machining experiments. International Journal of Advanced Manufacturing Technology, , s00170-024-13087-9/1-s00170-024-13087-9/16 (2024) 10.1007/s00170-024-13087-9 IF=2.9 Q2
14. 
    Wisnom M.R., Pimenta S., Shaffer M.S.P., Robinson P., Potter K.D., Hamerton I., Czél G., Jalalvand M., Fotouhi M., Anthony D.B., Yu H., Longana M.L., Wu X., Bismarck A.: High performance ductile and pseudo-ductile polymer matrix composites: A review. Composites Part A: Applied Science and Manufacturing, 181, 108029/1-108029/39 (2024) 10.1016/j.compositesa.2024.108029 IF=8.1 Q1
15. 
    Molnár K.: Combination of nanofibers with 3D-printed or 4D-printed structures. Express Polymer Letters, 18, 243-244 (2024) 10.3144/expresspolymlett.2024.17 IF=2.7 Q2
16. 
    Czél G.: Development of sandwich test coupons with continuous protective layers for accurate determination of the tensile failure strain of unidirectional carbon fibre reinforced composites. Composites Part A: Applied Science and Manufacturing, 187, 108440/1-108440/12 (2024) 10.1016/j.compositesa.2024.108440 IF=8.1 Q1
17. 
    Virág Á. D., Juhász Zs., Kossa A., Molnár K.: Combining oscillatory shear rheometry and dynamic mechanical analysis to obtain wide-frequency master curves. Polymer, 295, 126742/1-126742/11 (2024) https://doi.org/10.1016/j.polymer.2024.126742 IF=4.1 Q2
18. 
    Pomázi Á., Poór D. I., Geier N., Toldy A.: Optimising Recycling Processes for Polyimine-Based Vitrimer Carbon Fibre-Reinforced Composites: A Comparative Study on Reinforcement Recovery and Material Properties. Materials, 17(10), 2372/1-2372/15 (2024) 10.3390/ma17102372 IF=3.1 Q1
19. 
    Juhász Á. Gy., Nanys M., Pinke B., Fadel A., Godzierz M., Juriga-Tóth K., Molnár K., Juriga D., Jedlovszky-Hajdú A.: Formation of Three-Dimensional PolysuccinimideElectrospun Fiber Meshes Induced by the Combination ofCaCl2and Humidity. Macromolecular Rapid Communications, , 2300625/1-2300625/12 (2024) 10.1002/marc.202300625 IF=4.2 Q2
20. 
    Zielinski D., Szpecht A., Pomázi Á., Kovács Zs., Szolnoki B., Pinke B., Toldy A., Smiglak M.: Multifunctional modifying systems based on ionic liquids for epoxy resin systems and composites. Applied Sciences-Basel, 13, 10661/1-10661/ (2023) 10.3390/app131910661 IF=2.5 Q1
21. 
    Gere D., Toldy A.: Az EU két éve betiltotta az oxidatív úton lebomló, széttöredező polimerből készülttermékeket, amelyek hozzájárultak a mikroműanyagok keletkezéséhez.
22. 
    Tamás-Bényei P.: The effect of salt water on the properties of basalt fibre reinforced composites. Acta Materialia Transylvanica, 6., 105-113 (2023) 10.33924/amt-2023-02-08
23. 
    Toldy A.: Challenges and opportunities of polymer recycling in the changing landscape of European legislation.